1.23.1.1: (+)-pinoresinol reductase
This is an abbreviated version!
For detailed information about (+)-pinoresinol reductase, go to the full flat file.
Word Map on EC 1.23.1.1
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1.23.1.1
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lignans
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secoisolariciresinol
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linum
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podophyllotoxin
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forsythia
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+-pinoresinol
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usitatissimum
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intermedia
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album
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dirigent
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matairesinol
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diglucoside
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flax
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heartwood
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podophyllum
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lignify
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cinnamoyl-coa
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coniferyl
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phenylcoumaran
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cinnamyl-alcohol
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sesamin
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cinnamyl
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methylenedioxy
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cedar
- 1.23.1.1
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lignans
- secoisolariciresinol
- linum
- podophyllotoxin
- forsythia
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+-pinoresinol
- usitatissimum
- intermedia
- album
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dirigent
- matairesinol
- diglucoside
- flax
-
heartwood
- podophyllum
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lignify
- cinnamoyl-coa
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coniferyl
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phenylcoumaran
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cinnamyl-alcohol
- sesamin
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cinnamyl
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methylenedioxy
- cedar
Reaction
Synonyms
(+)-pinoresinol reductase, (+)-pinoresinol-(+)-lariciresinol reductase, (+)-pinoresinol/(+)-lariciresinol reductase, (+)pinoresinol-(+)lariciresinol reductase, bi-functional pinoresinol/lariciresinol reductase, bifunctional pinoresinol-lariciresinol reductase 2, LuPLR2, More, pinoresinol reductase, pinoresinol reductase 2, pinoresinol-lariciresinol reductase, pinoresinol-lariciresinol reductase-2, pinoresinol/lariciresinol reductase, PinZ, PLR, PLR-La1, PLR-Lc1, PLR-Lu2, PLR-Tp2, PLR1, PLR2, PrR1, PrR2, RR-pinoresinol-RR-lariciresinol reductase
ECTree
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Substrates Products
Substrates Products on EC 1.23.1.1 - (+)-pinoresinol reductase
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REACTION DIAGRAM
(+)-pinoresinol + NADPH + H+
(+)-lariciresinol + NADP+
efficient substrate
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?
(+)-pinoresinol + NADPH + H+
(+)-lariciresinol + NADP+
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-
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?
(+)-pinoresinol + NADPH + H+
(+)-lariciresinol + NADP+
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the enzyme abstracts the 4 pro-R hydrogen form NADPH (but not the 4 pro-S hydrogen)
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-
?
(+)-pinoresinol + NADPH + H+
(+)-lariciresinol + NADP+
primary substrate
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-
?
(+)-pinoresinol + NADPH + H+
(+)-lariciresinol + NADP+
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-
-
?
(+/-)-lariciresinol + NADP+
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?
(+/-)-pinoresinol + NADPH + H+
(+/-)-lariciresinol + NADP+
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-
-
-
?
5,5'-dimethoxylariciresinol + NADP+
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-
-
-
?
(+/-)-syringaresinol + NADPH + H+
5,5'-dimethoxylariciresinol + NADP+
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-
-
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?
(+/-)-syringaresinol + NADPH + H+
5,5'-dimethoxylariciresinol + NADP+
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-
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?
?
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the activity toward (+/-)-lariciresinol is 35times lower than that of pinoresinol
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?
additional information
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the activity toward (+/-)-lariciresinol is 35times lower than that of pinoresinol
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additional information
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(+)-pinoresinol is successively converted into (-+)-lariciresinol and further into (-)-secoisolariciresinol by bifunctional enzyme PrR2, cf. EC 1.23.1.2
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?
additional information
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(+)-pinoresinol is successively converted into (-+)-lariciresinol and further into (-)-secoisolariciresinol by bifunctional enzyme PrR2, cf. EC 1.23.1.2
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?
additional information
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(-)-pinoresinol does not serve as substrate
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?
additional information
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sesamin is not reduced by the enzyme
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?
additional information
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the protein shows preference for (+)-pinoresinol (R,R configuration at C-atoms 8,8) in the first reaction step, but preference for (-)-lariciresinol (S,S configuration at C-atoms 8,8) in the second reaction step
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?
additional information
?
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the protein shows preference for (+)-pinoresinol (R,R configuration at C-atoms 8,8) in the first reaction step, but preference for (-)-lariciresinol (S,S configuration at C-atoms 8,8) in the second reaction step
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-
?
additional information
?
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(+)-pinoresinol is successively converted into (-+)-lariciresinol and further into (-)-secoisolariciresinol by bifunctional enzyme PrR2, cf. EC 1.23.1.2
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-
?
additional information
?
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(+)-pinoresinol is successively converted into (-+)-lariciresinol and further into (-)-secoisolariciresinol by bifunctional enzyme PrR2, cf. EC 1.23.1.2
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-
?
additional information
?
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negligible activity with (+/-)-lariciresinol compared to (+/-)-pinoresinol
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?
additional information
?
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negligible activity with (+/-)-lariciresinol compared to (+/-)-pinoresinol
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additional information
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negligible activity with (+/-)-lariciresinol compared to (+/-)-pinoresinol
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?
additional information
?
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(-/+)-pinoresinol is successively converted into (-/+)-lariciresinol and (-/+)-secoisolariciresinol by enzyme PinZ
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?