1.14.14.41: (E)-2-methylbutanal oxime monooxygenase

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For detailed information about (E)-2-methylbutanal oxime monooxygenase, go to the full flat file.

Reaction

Synonyms

CYP71E7

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.14.41 (E)-2-methylbutanal oxime monooxygenase

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Results	in table
1	AA Sequence
1	Cofactor
1	General Information
1	Inhibitors
1	KM Value [mM]
2	Organism
3	Pathway
8	Reaction
2	Reference
6	Source Tissue
11	Substrates and Products (Substrate)
3	Synonyms
1	Systematic Name
4	Turnover Number [1/s]

Substrates Products

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Substrates Products on EC 1.14.14.41 - (E)-2-methylbutanal oxime monooxygenase

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SUBSTRATE

PRODUCT                       

REACTION DIAGRAM

ORGANISM

UNIPROT

COMMENTARY
(Substrate)

LITERATURE
(Substrate)

COMMENTARY
(Product)

LITERATURE
(Product)

Reversibility
r=reversible
ir=irreversible
?=not specified

(E)-2-methylbutanal oxime

(Z)-2-methylbutanal oxime

Manihot esculenta

Q6XQ14

-

741198

-

-

?

(E)-2-methylbutanal oxime + [reduced NADPH-hemoprotein reductase] + O2

2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O

Manihot esculenta

Q6XQ14

i.e. isoleucine-derived oxime

741198

overall reaction

-

?

(E)-2-methylpropanal oxime

(Z)-2-methylpropanal oxime

Manihot esculenta

Q6XQ14

-

741198

-

-

?

(E)-2-methylpropanal oxime + [reduced NADPH-hemoprotein reductase] + O2

2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O

Manihot esculenta

Q6XQ14

i.e. valine-derived oxime

741198

overall reaction

-

?

(Z)-2-methylbutanal oxime

2-methylbutanenitrile + H2O

Manihot esculenta

Q6XQ14

-

741198

-

-

?

(Z)-2-methylpropanal oxime

2-methylpropanenitrile + H2O

Manihot esculenta

Q6XQ14

-

741198

-

-

?

2-methylbutanenitrile + [reduced NADPH-hemoprotein reductase] + O2

2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O

Manihot esculenta

Q6XQ14

-

741198

-

-

?

2-methylpropanenitrile + [reduced NADPH-hemoprotein reductase] + O2

2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O

Manihot esculenta

Q6XQ14

-

741198

-

-

?

N-hydroxy-2-(4-hydroxypheny)-lethanimine + [reduced NADPH-hemoprotein reductase] + O2

(4-hydroxyphenyl)acetonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O

Manihot esculenta

Q6XQ14

i.e. phenylalanine-derived oxime

741198

overall reaction

-

?

N-hydroxy-2-phenylethanimine + [reduced NADPH-hemoprotein reductase] + O2

phenylacetonitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O

Manihot esculenta

Q6XQ14

i.e. phenylalanine-derived oxime

741198

overall reaction

-

?

additional information

?

-

2 entries

additional information

?

-

Manihot esculenta

Q6XQ14

CYP71E7 exhibits low specificity for the side chain of the substrate and catalyzes the conversion of aliphatic and aromatic oximes

741198

-

-

?

additional information

?

-

Manihot esculenta

-

CYP71E7 exhibits low specificity for the side chain of the substrate and catalyzes the conversion of aliphatic and aromatic oximes

741198

-

-

?