1.14.14.41: (E)-2-methylbutanal oxime monooxygenase

This is an abbreviated version!
For detailed information about (E)-2-methylbutanal oxime monooxygenase, go to the full flat file.

Reaction

+ 2 H2O

Synonyms

CYP71E7

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.14 With reduced flavin or flavoprotein as one donor, and incorporation of one atom of oxygen into the other donor

1.14.14.41 (E)-2-methylbutanal oxime monooxygenase

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11	Substrates and Products (Substrate)
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Reaction

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Reaction on EC 1.14.14.41 - (E)-2-methylbutanal oxime monooxygenase

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(E)-2-methylbutanal oxime + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O

(1) overall reaction

(E)-2-methylbutanal oxime = (Z)-2-methylbutanal oxime

(1a)

(E)-2-methylpropanal oxime + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + 2 H2O

(2) overall reaction

(E)-2-methylpropanal oxime = (Z)-2-methylpropanal oxime

(2a)

(Z)-2-methylbutanal oxime = 2-methylbutanenitrile + H2O

(1b)

(Z)-2-methylpropanal oxime = 2-methylpropanenitrile + H2O

(2b)

2-methylbutanenitrile + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylbutanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O

(1c)

2-methylpropanenitrile + [reduced NADPH-hemoprotein reductase] + O2 = 2-hydroxy-2-methylpropanenitrile + [oxidized NADPH-hemoprotein reductase] + H2O

catalytic reaction mechanism, detailed overview