1.14.13.105: monocyclic monoterpene ketone monooxygenase
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For detailed information about monocyclic monoterpene ketone monooxygenase, go to the full flat file.
Reaction
Synonyms
Baeyer-Villiger mono-oxygenase, Baeyer-Villiger monooxygenase, BVMO, dihydrocarvone 1,2-monooxygenase, MMKMO, monocyclic monoterpene ketone mono-oxygenase, NADPH-dependent 1-hydroxy-2-oxolimonene 1,2-monooxygenase, NADPH-dependent dihydrocarvone monooxygenase
ECTree
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Systematic Name
Systematic Name on EC 1.14.13.105 - monocyclic monoterpene ketone monooxygenase
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(-)-menthone,NADPH:oxygen oxidoreductase
A flavoprotein (FAD). This Baeyer-Villiger monooxygenase enzyme from the Gram-positive bacterium Rhodococcus erythropolis DCL14 has wide substrate specificity, catalysing the lactonization of a large number of monocyclic monoterpene ketones and substituted cyclohexanones [2]. Both (1R,4S)- and (1S,4R)-1-hydroxymenth-8-en-2-one are metabolized, with the lactone product spontaneously rearranging to form 3-isopropenyl-6-oxoheptanoate [1].