1.1.1.269: 2-(S)-hydroxypropyl-CoM dehydrogenase

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For detailed information about 2-(S)-hydroxypropyl-CoM dehydrogenase, go to the full flat file.

Word Map on EC 1.1.1.269

1.1.1.269

epoxide

stereoselectivity

autotrophicus

xanthobacter

achiral

s-enantiomers

ketones

enantioselectivity

product-bound

propylene

epoxypropane

acetoacetate

2-butanone

Reaction

Synonyms

(S)-hydroxypropyl-coenzyme M dehydrogenase, (S)-hydroxypropylthioethanesulfonate dehydrogenase, 2-(2-(S)-hydroxypropylthio)ethanesulfonate dehydrogenase, HPCDH3, S-HPCDH, xecE, xecE1, xecE3

ECTree

1 Oxidoreductases

1.1 Acting on the CH-OH group of donors

1.1.1 With NAD⁺ or NADP⁺ as acceptor

1.1.1.269 2-(S)-hydroxypropyl-CoM dehydrogenase

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Results	in table
189	AA Sequence
1	CAS Registry Number
1	Cloned(Commentary)
6	Cofactor
2	Crystallization (Commentary)
8	General Information
1	Inhibitors
20	kcat/KM [mM/s]
2	Ki Value [mM]
21	KM Value [mM]
5	Natural Substrates/ Products (Substrates)
17	Organism
1	Pathway
6	Protein Variants
1	Purification (Commentary)
4	Reaction
3	Reaction Type
7	Reference
2	Source Tissue
22	Substrates and Products (Substrate)
15	Synonyms
1	Systematic Name
21	Turnover Number [1/s]

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Reference on EC 1.1.1.269 - 2-(S)-hydroxypropyl-CoM dehydrogenase

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389508

Krum, J.G.; Ensign, S.A.

Evidence that a linear megaplasmid encodes enzymes of aliphatic alkene and epoxide metabolism and coenzyme M (2-mercaptoethanesulfonate) biosynthesis in Xanthobacter strain Py2

J. Bacteriol.

183

2172-2177

2001

Xanthobacter sp., Xanthobacter sp. Py2

11244054

667740

Krishnakumar, A.M.; Nocek, B.P.; Clark, D.D.; Ensign, S.A.; Peters, J.W.

Structural basis for stereoselectivity in the (R)- and (S)-hydroxypropylthioethanesulfonate dehydrogenases

Biochemistry

8831-8840

2006

Xanthobacter autotrophicus

16846226

711235

Sliwa, D.A.; Krishnakumar, A.M.; Peters, J.W.; Ensign, S.A.

Molecular basis for enantioselectivity in the (R)- and (S)-hydroxypropylthioethanesulfonate dehydrogenases, a unique pair of stereoselective short-chain dehydrogenases/reductases involved in aliphatic epoxide carboxylation

Biochemistry

3487-3498

2010

Xanthobacter autotrophicus, Xanthobacter autotrophicus (Q56841)

20302306

724129

Bakelar, J.W.; Sliwa, D.A.; Johnson, S.J.

Crystal structures of S-HPCDH reveal determinants of stereospecificity for R- and S-hydroxypropyl-coenzyme M dehydrogenases

Arch. Biochem. Biophys.

533

62-68

2013

Xanthobacter autotrophicus (A7IQH5), Xanthobacter autotrophicus

23474457

762714

Clark, D.D.

Characterization of the recombinant (R)- and (S)-hydroxypropyl-coenzyme M dehydrogenases A case study to augment the teaching of enzyme kinetics and stereoselectivity

Biochem. Mol. Biol. Educ.

124-132

2019

Xanthobacter autotrophicus (Q56841), Xanthobacter autotrophicus ATCC BAA-1158 (Q56841)

30592559