Reaction catalyzed by acireductone synthase (3.1.3.77), 2,3-diketo-5-methylthiopentyl-1-phosphate enolase (5.3.2.5) show all sequences for 5.3.2.5
=
5-(methylsulfanyl)-2,3-dioxopentyl phosphate
=
2-hydroxy-5-(methylsulfanyl)-3-oxopent-1-enyl phosphate