Reaction catalyzed by 10-deoxymethynolide synthase (2.3.1.239)
+
=
+
+
CoA
+
+
NADP+
+
H2O
methylmalonyl-N-acetylcysteamine
+
S-phenyl (2S,4R,6E,8R,9R)-9-hydroxy-2,4,8-trimethyl-5-oxoundec-6-enethioate
=
3-dehydro-10-deoxymethynolide
+
10-deoxymethynolide
+
CoA
+
CO2
+
NADP+
+
H2O
