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EC Number
Substrates
Commentary Substrates
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5.5.1.B6
aklanonic acid methyl ester
-
Streptomyces galilaeus
?
-
?
5.5.1.B6
nogalonic acid methyl ester
-
Streptomyces galilaeus
auraviketone
product has (R)-configuration at C9, ring closure is an intramolecular aldol condensation. The attack of the enol(ate) is on the si face of the C9 carbonyl group, required for the formation of the C9-R stereoisomer, which results in the alcoholate anion pointing away from the carboxyl side-chain of Asp121
?
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