EC Number   |
Reaction |
Reference |
|---|
  4.2.3.18 | (+)-copalyl diphosphate = abieta-7,13-diene + diphosphate |
- |
- |
| 4.2.3.18 | (+)-copalyl diphosphate = abieta-7,13-diene + diphosphate |
gas-phase and enzyme-free post-transition state direct dynamics simulation gas-phase reveal that abietadiene synthase must intervene in order to produce abietadiene selectively, steering this reaction to avoid the generation of a sevenmembered ring containing product which is formed in the enzyme-free reaction |
715305 |
| 4.2.3.18 | (+)-copalyl diphosphate = abieta-7,13-diene + diphosphate |
reaction mechanism proceeds via water quenching of the abieta-8(14)-en-13-yl carbocation, resulting in 13-hydroxy-8(14)-abietene |
715611 |
| 4.2.3.18 | (+)-copalyl diphosphate = abieta-7,13-diene + diphosphate |
reactions leading from intermediate abieta-8(14)-en-13-yl cation to product are driven by the electrostatic effect of the ionized diphopshate group |
680365 |
