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Literature summary extracted from

  • Sello, G.; Di Gennaro, P.
    Aldol reactions of the trans-o-hydroxybenzylidenepyruvate hydratase-aldolase (tHBP-HA) from Pseudomonas fluorescens N3 (2013), Appl. Biochem. Biotechnol., 170, 1702-1712.
    View publication on PubMed

Organism

EC Number Organism UniProt Comment Textmining
4.1.2.45 Pseudomonas fluorescens
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-
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4.1.2.45 Pseudomonas fluorescens N3
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.2.45 2-nitrobenzaldehyde + pyruvate
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Pseudomonas fluorescens 4-(2-nitrophenyl)-2-oxobut-3-enoate + H2O
-
?
4.1.2.45 2-nitrobenzaldehyde + pyruvate
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Pseudomonas fluorescens N3 4-(2-nitrophenyl)-2-oxobut-3-enoate + H2O
-
?
4.1.2.45 3-phenylpropionaldehyde + pyruvate
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Pseudomonas fluorescens 3-hydroxy-5-(2-phenylethyl)furan-2(5H)-one + H2O
-
?
4.1.2.45 3-phenylpropionaldehyde + pyruvate
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Pseudomonas fluorescens N3 3-hydroxy-5-(2-phenylethyl)furan-2(5H)-one + H2O
-
?
4.1.2.45 4-nitrobenzaldehyde + pyruvate
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Pseudomonas fluorescens 4-(4-nitrophenyl)-2-oxobut-3-enoate + H2O
-
?
4.1.2.45 benzaldehyde + pyruvate
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Pseudomonas fluorescens benzylidenepyruvate + H2O
-
?
4.1.2.45 benzaldehyde + pyruvate
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Pseudomonas fluorescens N3 benzylidenepyruvate + H2O
-
?
4.1.2.45 cinnamaldehyde + pyruvate
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Pseudomonas fluorescens (3E,5E)-2-oxo-6-phenylhexa-3,5-dienoic acid + H2O
-
?
4.1.2.45 additional information enzmye is strictly dependent on pyruvate as donor component. The structure of the products is highly dependent on the electronic characteristics of the aldehyde, and the formation of the furan derivatives is spontaneous during the work up procedure. No donors are: ethyl and methyl pyruvate, 2-oxobutanoic acid, acetyl acetone, and butane-2,3-dione. No acceptor components are: n-octanal, pivalaldehyde, and benzylideneacetone Pseudomonas fluorescens ?
-
?
4.1.2.45 additional information enzmye is strictly dependent on pyruvate as donor component. The structure of the products is highly dependent on the electronic characteristics of the aldehyde, and the formation of the furan derivatives is spontaneous during the work up procedure. No donors are: ethyl and methyl pyruvate, 2-oxobutanoic acid, acetyl acetone, and butane-2,3-dione. No acceptor components are: n-octanal, pivalaldehyde, and benzylideneacetone Pseudomonas fluorescens N3 ?
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?
4.1.2.45 phenylacetaldehyde + pyruvate
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Pseudomonas fluorescens 5-benzyl-3-hydroxyfuran-2(5H)-one + H2O
-
?
4.1.2.45 phthalaldehyde + pyruvate
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Pseudomonas fluorescens (3E)-4-(2-formylphenyl)-2-oxobut-3-enoate + H2O
-
?
4.1.2.45 phthalaldehyde + pyruvate
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Pseudomonas fluorescens N3 (3E)-4-(2-formylphenyl)-2-oxobut-3-enoate + H2O
-
?
4.1.2.45 salicylaldehyde + pyruvate
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Pseudomonas fluorescens trans-o-hydroxybenzylidenepyruvate + H2O
-
?
4.1.2.45 terephthalaldehyde + pyruvate
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Pseudomonas fluorescens 4-(4-hydroxy-5-oxo-2,5-dihydrofuran-2-yl)benzaldehyde + H2O 25% of products ?