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Literature summary extracted from

  • Schmidt, M.; Herve, S.; KLempier, N.; Griengl, H.
    Preparation of optically active cyanohydrins using the (S)-hydroxynitrile lyase from Hevea brasiliensis (1996), Tetrahedron, 52, 7833-7840.
No PubMed abstract available

Organism

EC Number Organism UniProt Comment Textmining
4.1.2.47 Hevea brasiliensis P52704 recombinant
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Substrates and Products (Substrate)

EC Number Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
4.1.2.47 cyanide + 2-methoxybenzaldehyde
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 Hevea brasiliensis (2S)-2-hydroxy-2-(2-methoxyphenyl)acetonitrile 77% enantiomeric excess ?
4.1.2.47 cyanide + 3-methoxybenzaldehyde
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 Hevea brasiliensis (2S)-2-hydroxy-2-(3-methoxyphenyl)acetonitrile 99% enantiomeric excess ?
4.1.2.47 cyanide + 3-phenoxybenzaldehyde
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 Hevea brasiliensis (2S)-2-hydroxy-2-(3-phenoxyphenyl)acetonitrile 99% enantiomeric excess ?
4.1.2.47 cyanide + 3-phenylpropanal
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 Hevea brasiliensis (2S)-2-hydroxy-4-phenylbutanenitrile 93% enantiomeric excess ?
4.1.2.47 cyanide + 4-methoxybenzaldehyde
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 Hevea brasiliensis (2S)-2-hydroxy-2-(4-methoxyphenyl)acetonitrile 95% enantiomeric excess ?
4.1.2.47 cyanide + benzaldehyde
-
 Hevea brasiliensis (2S)-2-hydroxy-2-phenylacetonitrile i.e. (S)-mandelonitrile, more than 99% enantiomeric excess ?
4.1.2.47 cyanide + cinnamaldehyde
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 Hevea brasiliensis (2S)-2-hydroxy-4-phenyl-(E)-but-3-enenitrile 95% enantiomeric excess ?
4.1.2.47 cyanide + cyclohex-3-ene-1-carbaldehyde
-
 Hevea brasiliensis (2S)-2-(cyclohex-3-enyl)-2-hydroxyacetonitrile 99% enantiomeric excess ?
4.1.2.47 cyanide + cyclohexanecarbaldehyde
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 Hevea brasiliensis (2S)-2-cyclohexyl-2-hydroxyacetonitrile 99% enantiomeric excess ?
4.1.2.47 cyanide + phenylacetaldehyde
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 Hevea brasiliensis (2S)-2-hydroxy-3-phenylpropanenitrile 99% enantiomeric excess ?

Synonyms

EC Number Synonyms Comment Organism
4.1.2.47 (S)-Hydroxynitrile lyase
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 Hevea brasiliensis