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Literature summary for 5.5.1.8 extracted from

  • Croteau, R.; Satterwhite, D.M.; Cane, D.E.; Chang, C.C.
    Biosynthesis of monoterpenes. Enantioselectivity in the enzymatic cyclization of (+)- and (-)-linalyl pyrophosphate to (+)- and (-)-bornyl pyrophosphate (1986), J. Biol. Chem., 261, 13438-13445.
    View publication on PubMed

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.0007
-
(-)-(3R)-linalyl diphosphate
-
Salvia officinalis
0.0011
-
geranyl diphosphate
-
Salvia officinalis
0.0023
-
geranyl diphosphate
-
Tanacetum vulgare
0.0032
-
(+)-(3S)-linalyl diphosphate
-
Salvia officinalis
0.0037
-
neryl diphosphate
-
Tanacetum vulgare
0.007
-
(+)-(3S)-linalyl diphosphate
-
Tanacetum vulgare
0.0121
-
neryl diphosphate
-
Salvia officinalis

Organism

Organism UniProt Comment Textmining
Salvia officinalis
-
-
-
Tanacetum vulgare
-
-
-

Source Tissue

Source Tissue Comment Organism Textmining
leaf epidermis Salvia officinalis
-
leaf epidermis Tanacetum vulgare
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(+)-(3S)-Linalyl diphosphate
-
Salvia officinalis (-)-(1S,4S)-Bornyl-diphosphate
-
?
(+)-(3S)-Linalyl diphosphate
-
Tanacetum vulgare (-)-(1S,4S)-Bornyl-diphosphate
-
?
(-)-(3R)-Linalyl diphosphate
-
Salvia officinalis (+)-(1R,4R)-Bornyl-diphosphate
-
?
Geranyl diphosphate
-
Salvia officinalis (+)-Bornyl-diphosphate (+)-(1R,4R)-bornyl-diphosphate ?
Geranyl diphosphate
-
Tanacetum vulgare (-)-Bornyl-diphosphate (-)-(1S,4S)-bornyl-diphosphate ?
Neryl diphosphate
-
Tanacetum vulgare (+)-Bornyl-diphosphate
-
?
Neryl diphosphate
-
Salvia officinalis (+)-Bornyl-diphosphate (+)-(1R,4R)-bornyl diphosphate ?