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Literature summary for 5.5.1.22 extracted from

  • Croteau, R.; Gershenzon, J.; Wheeler, C.J.; Satterwhite, D.M.
    Biosynthesis of monoterpenes: stereochemistry of the coupled isomerization and cyclization of geranyl pyrophosphate to camphane and isocamphane monoterpenes (1990), Arch. Biochem. Biophys., 277, 374-381.
    View publication on PubMed

Molecular Weight [Da]

Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
65000
-
-
Tanacetum vulgare

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
geranyl diphosphate Tanacetum vulgare
-
(-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?

Organism

Organism UniProt Comment Textmining
Tanacetum vulgare
-
-
-

Purification (Commentary)

Purification (Comment) Organism
-
Tanacetum vulgare

Source Tissue

Source Tissue Comment Organism Textmining
leaf
-
Tanacetum vulgare
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(3S)-linalyl diphosphate
-
Tanacetum vulgare (-)-bornyl diphosphate
-
?
geranyl diphosphate
-
Tanacetum vulgare (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?
geranyl diphosphate isomerization and cyclization takes place at the same active site Tanacetum vulgare (-)-bornyl diphosphate i.e. (2R,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl diphosphate ?

Synonyms

Synonyms Comment Organism
(-)-bornyl pyrophosphate cyclase
-
Tanacetum vulgare