Metals/Ions | Comment | Organism | Structure |
---|---|---|---|
Mn2+ | required | Pseudomonas putida |
Natural Substrates | Organism | Comment (Nat. Sub.) | Natural Products | Comment (Nat. Pro.) | Rev. | Reac. |
---|---|---|---|---|---|---|
cis,cis-Muconate | Pseudomonas putida | enzyme of the benzoate catabolism | ? | - |
? |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Pseudomonas putida | - |
- |
- |
Reaction | Comment | Organism | Reaction ID |
---|---|---|---|
(+)-muconolactone = cis,cis-muconate | in the reverse reaction the alpha proton of muconolactone is abstracted by a homolog of Lys166(Lys169) to generate an enolic intermediate, this intermediate undergoes vinylopous beta-elimination of the remote carboxylate group to produce cis,cis-muconate | Pseudomonas putida |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
cis,cis-Muconate | i.e. cis,cis-2,4-hexadiendioate, , r | Pseudomonas putida | (+)-Muconolactone | - |
? | |
cis,cis-Muconate | enzyme of the benzoate catabolism | Pseudomonas putida | ? | - |
? |