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Literature summary for 5.4.99.39 extracted from

  • Noma, H.; Tanaka, H.; Noguchi, H.; Shibuya, M.; Ebizuka, Y.; Abe, I.
    Enzymatic formation of an unnatural novel tetracyclic sesterterpene by beta-amyrin synthase (2004), Tetrahedron Lett., 45, 8299-8301.
No PubMed abstract available

Application

Application Comment Organism
synthesis use of enzyme for production of unnatural tetracyclic sesterterpenes Pisum sativum

Cloned(Commentary)

Cloned (Comment) Organism
-
Pisum sativum

Organism

Organism UniProt Comment Textmining
Pisum sativum
-
recombinant protein
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(3R)-2,2-dimethyl-3-[(3E,7E,11E)-3,7,12,16-tetramethylheptadeca-3,7,11,15-tetraen-1-yl]oxirane pre-chair-chair-chair-boat conformation of substrate Pisum sativum (3alpha,9xi,10alpha)-4,4,14,20-tetramethylpregn-7-en-3-ol about 1% of the yield with substrate 24,30-bisnor-2,3-oxidosqualene ?
22,23-dihydro-2,3-oxidosqualene
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Pisum sativum euph-7-en-3beta-ol + bacchar-12-en-3beta-ol about 10% of the yield with substrate 24,30-bisnor-2,3-oxidosqualene ?
24,30-bisnor-2,3-oxidosqualene
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Pisum sativum 29,30-bisnor-beta-amyrin + 29,30-bisnorgermanicol + 29,30-bisnor-delta-amyrin
-
?