Literature summary for 5.4.4.6 extracted from

Hamberg, M.; Zhang, L.Y.; Brodowsky, I.D.; Oliw, E.H.
Sequential oxygenation of linoleic acid in the fungus Gaeumannomyces graminis: Stereochemistry of dioxygenase and hydroperoxide isomerase reactions (1994), Arch. Biochem. Biophys., 309, 77-80.

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Natural Substrates/ Products (Substrates)

Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.	Reac.
(8R,9Z,12Z)-8-hydroperoxy-10,12-octadecadienoate	Gaeumannomyces graminis	-	(7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-10,12-octadecadienoate	Gaeumannomyces graminis var.graminis	-	(7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	Gaeumannomyces graminis	-	(7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	Gaeumannomyces graminis var.graminis	-	(7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate	-	?

Organism

Organism	UniProt	Comment	Textmining
Gaeumannomyces graminis	-	-	-
Gaeumannomyces graminis var.graminis	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(8R,9Z,12Z)-8-hydroperoxy-10,12-octadecadienoate	-	Gaeumannomyces graminis	(7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-10,12-octadecadienoate	-	Gaeumannomyces graminis var.graminis	(7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	Gaeumannomyces graminis	(7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	Gaeumannomyces graminis var.graminis	(7S,8S,9Z,12Z)-7,8-dihydroxy-9,12-octadecadienoate	-	?
(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	conversion of (8R)-hydroperoxylinoleic acid into (7S,8S)-dihydroxylinoleic acid by stereospecific elimination of the pro-S hydrogen from C-7 and intramolecular suprafacial insertion of oxygen at C-7	Gaeumannomyces graminis	(7S,8S,9Z,12Z)-7,8-dihydroxyoctadeca-9,12-dienoate	-	?

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Release 2023.1 (January 2023)