Literature summary for 4.4.1.4 extracted from

Krest, I.; Glodek, J.; Keusgen, M.
Cysteine sulfoxides and alliinase activity of some Allium species (2000), J. Agric. Food Chem., 48, 3753-3760.

KM Value [mM]

KM Value [mM]	KM Value Maximum [mM]	Substrate	Comment	Organism
0.42	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium victorialis
0.47	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium saxatile
0.68	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium stipitatum
0.77	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium obliquum
0.85	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium subhirsutum
1.25	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium sativum
1.48	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium hymenorrhizum
1.59	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium sphaerocephalon
1.79	-	(+)-S-(2-propenyl)-L-cysteine sulfoxide	pH 7.0, 25°C	Allium jesdianum

Natural Substrates/ Products (Substrates)

Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.
additional information	Allium sativum	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium sphaerocephalon	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium victorialis	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium hymenorrhizum	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium saxatile	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium obliquum	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium subhirsutum	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium jesdianum	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?
additional information	Allium stipitatum	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	?	-	?

Organism

Organism	UniProt	Comment	Textmining
Allium hymenorrhizum	-	-	-
Allium jesdianum	-	-	-
Allium obliquum	-	-	-
Allium sativum	-	-	-
Allium saxatile	-	-	-
Allium sphaerocephalon	-	-	-
Allium stipitatum	-	-	-
Allium subhirsutum	-	-	-
Allium victorialis	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium sativum	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium sphaerocephalon	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium victorialis	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium hymenorrhizum	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium saxatile	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium obliquum	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium subhirsutum	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium jesdianum	2-propene-thioic acid + pyruvate + ammonia	-	?
(+)-S-(2-propenyl)-L-cysteine sulfoxide	-	Allium stipitatum	2-propene-thioic acid + pyruvate + ammonia	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sphaerocephalon	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium jesdianum	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sativum	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium hymenorrhizum	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium subhirsutum	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium obliquum	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium saxatile	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium stipitatum	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(1-methyl)-L-cysteine sulfoxide	about 45% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium victorialis	methanesulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium subhirsutum	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sativum	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sphaerocephalon	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	6.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium victorialis	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	7% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium jesdianum	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	8% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium hymenorrhizum	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium saxatile	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium obliquum	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(butyl)-L-cysteine sulfoxide	about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium stipitatum	butane-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sativum	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sphaerocephalon	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium victorialis	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	4% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium hymenorrhizum	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	7% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium subhirsutum	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	about 10% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium stipitatum	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	about 20% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium jesdianum	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	about 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium saxatile	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(+/-)-(propyl)-L-cysteine sulfoxide	about 5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium obliquum	propyl-1-sulfenic acid + pyruvate + NH3	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 15% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium subhirsutum	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 20% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sativum	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium hymenorrhizum	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium obliquum	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 3.5% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sphaerocephalon	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium victorialis	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium saxatile	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium jesdianum	2-propene-thioic acid + pyruvate + ammonia	-	?
(-)-(2-propenyl)-L-cysteine sulfoxide	about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium stipitatum	2-propene-thioic acid + pyruvate + ammonia	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium sativum	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium sphaerocephalon	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium victorialis	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium hymenorrhizum	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium saxatile	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium obliquum	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium subhirsutum	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium jesdianum	?	-	?
additional information	the enzyme catalyzes the conversion of odorless (+)-S-alk(en)yl-L-cysteine sulfoxides into volatile thiosulfinates	Allium stipitatum	?	-	?
additional information	no activity with (+/-)-(ethyl)-L-cysteine sulfoxide	Allium jesdianum	?	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sativum	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium sphaerocephalon	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 25% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium subhirsutum	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 30% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium hymenorrhizum	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 35% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium obliquum	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 50% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium saxatile	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 50% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium stipitatum	ethylsulfenic acid + pyruvate + NH3	-	?
S-ethyl-L-Cys sulfoxide + H2O	about 55% of the activity with (+)-S-(2-propenyl)-L-cysteine sulfoxide	Allium victorialis	ethylsulfenic acid + pyruvate + NH3	-	?

Temperature Optimum [°C]

Temperature Optimum [°C]	Temperature Optimum Maximum [°C]	Comment	Organism
36	-	-	Allium sphaerocephalon
36	-	-	Allium hymenorrhizum
38	-	-	Allium saxatile
38	-	-	Allium obliquum
38	-	-	Allium stipitatum
40	-	-	Allium sativum
40	-	-	Allium subhirsutum
44	-	-	Allium victorialis
48	-	-	Allium jesdianum

pH Optimum

pH Optimum Minimum	pH Optimum Maximum	Comment	Organism
7	-	-	Allium sativum
7	-	-	Allium sphaerocephalon
7.5	-	-	Allium victorialis
7.5	-	-	Allium hymenorrhizum
7.5	-	-	Allium saxatile
7.5	-	-	Allium obliquum
7.5	-	-	Allium subhirsutum
7.5	-	-	Allium jesdianum
7.5	-	-	Allium stipitatum

pH Range

pH Minimum	pH Maximum	Comment	Organism
5.5	8.5	half-maximal activity at pH 5.5 and at pH 8.5	Allium sativum
5.5	8.5	half-maximal activity at pH 5.5 and at pH 8.5	Allium victorialis
5.5	8.5	half-maximal activity at pH 5.5 and at pH 8.5	Allium saxatile
5.5	8.5	half-maximal activity at pH 5.5 and at pH 8.5	Allium obliquum
5.5	8.5	half-maximal activity at pH 5.5 and at pH 8.5	Allium stipitatum
5.5	8	half-maximal activity at pH 5.5 and at pH 8.0	Allium sphaerocephalon
6	8.5	half-maximal activity at pH 6.0 and at pH 8.5	Allium hymenorrhizum
6.5	8.5	half-maximal activity at pH 6.5 and at pH 8.5	Allium subhirsutum
6.5	8.5	half-maximal activity at pH 6.5 and at pH 8.5	Allium jesdianum