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Literature summary for 4.2.3.70 extracted from

  • Faraldos, J.A.; Wu, S.; Chappell, J.; Coates, R.M.
    Doubly deuterium-labeled patchouli alcohol from cyclization of singly labeled [2-(2)H(1)]farnesyl diphosphate catalyzed by recombinant patchoulol synthase (2010), J. Am. Chem. Soc., 132, 2998-3008.
    View publication on PubMed

Organism

Organism UniProt Comment Textmining
Pogostemon cablin
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(2E,6E)-farnesyl diphosphate + H2O reaction proceeds via an exocyclic [7,10:1,5]patchoul-4(12)-ene intermediate. Occurrence of a 1,3-hydride shift across the 5-membered ring Pogostemon cablin patchoulol + diphosphate
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