Literature summary for 4.2.3.67 extracted from

Prosser, I.M.; Adams, R.J.; Beale, M.H.; Hawkins, N.D.; Phillips, A.L.; Pickett, J.A.; Field, L.M.
Cloning and functional characterisation of a cis-muuroladiene synthase from black peppermint (Mentha x piperita) and direct evidence for a chemotype unable to synthesise farnesene (2006), Phytochemistry, 67, 1564-1571.

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Cloned(Commentary)

Cloned (Comment)	Organism
expression in Escherichia coli	Mentha x piperita

KM Value [mM]

KM Value [mM]	KM Value Maximum [mM]	Substrate	Comment	Organism	Structure
0.0019	-	(2E,6E)-farnesyl diphosphate	pH 7.2, 27°C	Mentha x piperita

Natural Substrates/ Products (Substrates)

Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.	Reac.
(2E,6E)-farnesyl diphosphate	Mentha x piperita	-	cis-muurola-3,5-diene + diphosphate	main products cis-muurola-3,5-diene at 45% and cis-muurola-4(14),5-diene at 43%, minor products gamma-cadinene at 7% and alpha-cadinene at 5%	?
(2E,6E)-farnesyl diphosphate	Mentha x piperita	-	cis-muurola-4(14),5-diene + diphosphate	main products cis-muurola-3,5-diene at 45% and cis-muurola-4(14),5-diene at 43%, minor products gamma-cadinene at 7% and alpha-cadinene at 5%	?

Organism

Organism	UniProt	Comment	Textmining
Mentha x piperita	Q5W283	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(2E,6E)-farnesyl diphosphate	-	Mentha x piperita	cis-muurola-3,5-diene + diphosphate	main products cis-muurola-3,5-diene at 45% and cis-muurola-4(14),5-diene at 43%, minor products gamma-cadinene at 7% and alpha-cadinene at 5%	?
(2E,6E)-farnesyl diphosphate	-	Mentha x piperita	cis-muurola-4(14),5-diene + diphosphate	main products cis-muurola-3,5-diene at 45% and cis-muurola-4(14),5-diene at 43%, minor products gamma-cadinene at 7% and alpha-cadinene at 5%	?

Synonyms

Synonyms	Comment	Organism
MxpSS1	-	Mentha x piperita

Turnover Number [1/s]

Turnover Number Minimum [1/s]	Turnover Number Maximum [1/s]	Substrate	Comment	Organism	Structure
0.18	-	(2E,6E)-farnesyl diphosphate	pH 7.2, 27°C	Mentha x piperita

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Release 2023.1 (January 2023)