Inhibitors | Comment | Organism | Structure |
---|---|---|---|
(+)-(1R)-N,N,4-trimethyl-3-cyclohexenamine | aza-analogue of terpenyl cation, uncompetitive | Salvia officinalis | |
(+)-dimethyl-[(1R)-4-methylcyclohex-3-en-1-yl]sulfonium iodide | thia-analogue of terpenyl cation, uncompetitive | Salvia officinalis | |
(-)-(1S)-N,N,4-trimethyl-3-cyclohexenamine | aza-analogue of terpenyl cation, uncompetitive | Salvia officinalis | |
(-)-dimethyl-[(1S)-4-methylcyclohex-3-en-1-yl]sulfonium iodide | thia-analogue of terpenyl cation, uncompetitive | Salvia officinalis |
KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
0.0016 | - |
geranyl diphosphate | pH 6.8, 31°C | Salvia officinalis | |
0.009 | - |
(RS)-alpha-terpinyl diphosphate | pH 6.8, 31°C | Salvia officinalis |
Metals/Ions | Comment | Organism | Structure |
---|---|---|---|
Mg2+ | preferred divalent cation, Km value about 3 mM | Salvia officinalis |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Salvia officinalis | - |
- |
- |
Purification (Comment) | Organism |
---|---|
partial | Salvia officinalis |
Source Tissue | Comment | Organism | Textmining |
---|---|---|---|
leaf | - |
Salvia officinalis | - |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(RS)-alpha-terpinyl diphosphate | - |
Salvia officinalis | limonene + diphosphate | about 90% limonene, 10% terpinolene. Enzyme is unable to discriminate between enantiomers of alpha-terpinyl diphosphate | ? | |
geranyl diphosphate | - |
Salvia officinalis | (+)-alpha-pinene + diphosphate | reaction proceeds via (3R)-linalyl diphosphate and the (4R)-alpha-terpinyl cation. Products are (+)-alpha-pinene, and lesser amounts of related olefins | ? |
Ki Value [mM] | Ki Value maximum [mM] | Inhibitor | Comment | Organism | Structure |
---|---|---|---|---|---|
0.0007 | - |
(-)-(1S)-N,N,4-trimethyl-3-cyclohexenamine | pH 6.8, 31°C, presence of diphosphate | Salvia officinalis | |
0.001 | - |
(+)-(1R)-N,N,4-trimethyl-3-cyclohexenamine | pH 6.8, 31°C, presence of diphosphate | Salvia officinalis | |
0.0011 | - |
(-)-(1S)-N,N,4-trimethyl-3-cyclohexenamine | pH 6.8, 31°C | Salvia officinalis | |
0.002 | - |
(+)-(1R)-N,N,4-trimethyl-3-cyclohexenamine | pH 6.8, 31°C | Salvia officinalis | |
0.004 | - |
(-)-dimethyl-[(1S)-4-methylcyclohex-3-en-1-yl]sulfonium iodide | pH 6.8, 31°C, presence of diphosphate | Salvia officinalis | |
0.0058 | - |
(+)-dimethyl-[(1R)-4-methylcyclohex-3-en-1-yl]sulfonium iodide | pH 6.8, 31°C, presence of diphosphate | Salvia officinalis | |
0.0071 | - |
(-)-dimethyl-[(1S)-4-methylcyclohex-3-en-1-yl]sulfonium iodide | pH 6.8, 31°C | Salvia officinalis | |
0.0092 | - |
(+)-dimethyl-[(1R)-4-methylcyclohex-3-en-1-yl]sulfonium iodide | pH 6.8, 31°C | Salvia officinalis |