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Literature summary for 4.2.3.115 extracted from
- Hydride shifts in the biosynthesis of the p-menthane monoterpenes alpha-terpinene, gamma-terpinene, and beta-phellandrene (1993), Arch. Biochem. Biophys., 301, 361-366.
Localization
| Localization | Comment | Organism | GeneOntology No. | Textmining |
|---|---|---|---|---|
| soluble | - |
Dysphania ambrosioides | - |
- |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Dysphania ambrosioides | - |
- |
- |
Reaction
| Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|
| geranyl diphosphate = alpha-terpinene + diphosphate | the isomerization-cyclization involves a 1,2-hydride shift in the terpinyl cation to the terpin-4-yl-cation | Dysphania ambrosioides |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| geranyl diphosphate | - |
Dysphania ambrosioides | alpha-terpinene + diphosphate | the isomerization-cyclization involves a 1,2-hydride shift in the terpinyl cation to the terpin-4-yl-cation | ? |  |
pH Optimum
| pH Optimum Minimum | pH Optimum Maximum | Comment | Organism |
|---|---|---|---|
| 6.4 | - |
- |
Dysphania ambrosioides |
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