Any feedback?
Literature summary for 4.2.1.B7 extracted from
- Hidden stereospecificity in the biosynthesis of divinyl ether fatty acids (2005), FEBS J., 272, 736-743.
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Clematis vitalba | - |
- |
- |
Source Tissue
| Source Tissue | Comment | Organism | Textmining |
|---|---|---|---|
| leaf | - |
Clematis vitalba | - |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| (9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate | generation of (8Z)-colneleic acid from the (8R)-deuterated (9S)-hydroperoxide is accompanied by retention (98%) of most of the deuterium label | Clematis vitalba | (8Z)-9-[(1E,3E)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O | i.e. (8Z)-colneleic acid | ? |  |
| additional information | irrespective of which hydroperoxide regioisomer served as the substrate, divinyl ether synthases abstracting the pro-R hydrogen generate divinyl ethers having an (E)-vinyl ether double bond, whereas enzymes abstracting the pro-S hydrogen produce divinyl ethers having a (Z)-vinyl ether double bond | Clematis vitalba | ? | - |
? | |
Use of this online version of BRENDA is free under the CC BY 4.0 license. See terms of use for full details.
Release 2023.1 (January 2023)
Legal
Curated at
Member of
