Literature summary for 4.2.1.92 extracted from

Hamberg, M.; Zhang, L.Y.; Brodowsky, I.D.; Oliw, E.H.
Sequential oxygenation of linoleic acid in the fungus Gaeumannomyces graminis: Stereochemistry of dioxygenase and hydroperoxide isomerase reactions (1994), Arch. Biochem. Biophys., 309, 77-80.

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Organism

Organism	UniProt	Comment	Textmining
Gaeumannomyces graminis	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(8R)-hydroperoxy-(9Z,12Z)-octadecadienoic acid	stereospecific elimination of the pro-S hydrogen from C-7 and intramolecular suprafacial insertion of oxygen at C-7 with retention of the absolute configuration at C-7	Gaeumannomyces graminis	(7S,8S)-dihydroxy-(9Z,12Z)-octadecadienoic acid + H2O	-	?
(8R)-hydroperoxy-(9Z,12Z)-octadecadienoic acid	stereospecific elimination of the pro-S hydrogen from C-7 and intramolecular suprafacial insertion of oxygen at C-7 with retention of the absolute configuration at C-7	Gaeumannomyces graminis var.graminis	(7S,8S)-dihydroxy-(9Z,12Z)-octadecadienoic acid + H2O	-	?

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Release 2023.1 (January 2023)