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Literature summary for 4.2.1.121 extracted from

  • Fahlstadius, P.; Hamberg, M.
    Stereospecific removal of the pro-R hydrogen at C-8 of (9S)-hydroperoxyoctadecadienoic acid in the biosynthesis of colneleic acid (1990), J. Chem. Soc. Perkin Trans., 1990, 2027-2030.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate Solanum tuberosum
-
(8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate Solanum tuberosum Bintje
-
(8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?

Organism

Organism UniProt Comment Textmining
Solanum tuberosum
-
Bintje
-
Solanum tuberosum Bintje
-
Bintje
-

Reaction

Reaction Comment Organism Reaction ID
(9S,10E,12Z)-9-hydroperoxyoctadeca-10,12-dienoate = (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoate + H2O selective removal of the pro-R hydrogen at C-8 in the biosynthesis of colneleic acid Solanum tuberosum

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate
-
Solanum tuberosum (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate selective removal of the pro-R hydrogen at C-8 in the biosynthesis of colneleic acid Solanum tuberosum (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate
-
Solanum tuberosum Bintje (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?
(9S,10E,12Z)-9-hydroperoxy-10,12-octadecadienoate selective removal of the pro-R hydrogen at C-8 in the biosynthesis of colneleic acid Solanum tuberosum Bintje (8E)-9-[(1E,3Z)-nona-1,3-dien-1-yloxy]non-8-enoic acid + H2O i.e. colneleate ?