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Literature summary for 4.1.99.11 extracted from
- Mechanism of benzylsuccinate synthase: Stereochemistry of toluene addition to fumarate and maleate (2005), J. Am. Chem. Soc., 127, 8608-8609.
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Thauera aromatica | - |
- |
- |
Source Tissue
| Source Tissue | Comment | Organism | Textmining |
|---|---|---|---|
| culture condition:toluene-grown cell | - |
Thauera aromatica | - |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| [d3-methyl]toluene + fumarate | deuterium is transferred from toluene to the C-3 pro-(S) position of benzylsuccinate, implying that the addition of toluene to the double bond of fumarate is syn | Thauera aromatica | ? | - |
? |  |
| [d3-methyl]toluene + maleate | addition of toluene occurs in anti fashion. Formation of the C-3 radical of the benzylsuccinate as an intermediate, in which rotation about the C-2-C-3 bond can occur to relieve the sterically unfavorable cis conformation | Thauera aromatica | ? | - |
? | |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| BSS | - |
Thauera aromatica |
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Release 2023.1 (January 2023)
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