Literature summary for 4.1.2.47 extracted from

Xu, R.; Zong, M.H.; Liu, Y.Y.; He, J.; Zhang, Y.Y.; Lou, W.Y.
Enzymatic enantioselective transcyanation of silicon-containing aliphatic ketone with (S)-hydroxynitrile lyase from Manihot esculenta (2004), Appl. Microbiol. Biotechnol., 66, 27-33.

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KM Value [mM]

KM Value [mM]	KM Value Maximum [mM]	Substrate	Comment	Organism	Structure
61.5	-	acetyltrimethylsilane	pH 5.4, 40°C	Manihot esculenta
161.5	-	3,3-dimethyl-2-butanone	pH 5.4, 40°C	Manihot esculenta

Organism

Organism	UniProt	Comment	Textmining
Manihot esculenta	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
3,3-dimethyl-2-butanone + acetone cyanohydrin	transcyanation	Manihot esculenta	(S)-2-hydroxy-2-methyl-3,3-dimethyl-butyronitrile	-	?
acetyltrimethylsilane + acetone cyanohydrin	transcyanation	Manihot esculenta	(S)-2-trimethylsilyl-2-hydroxyl-propionitrile + acetone	-	?

Synonyms

Synonyms	Comment	Organism
MeHNL	-	Manihot esculenta

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Release 2023.1 (January 2023)