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Literature summary for 4.1.2.10 extracted from

  • Fechter, M.H.; Gruber, K.; Avi, M.; Skranc, W.; Schuster, C.; Pöchlauer, P.; Klepp, K.O.; Griengl, H.
    Stereoselective biocatalytic synthesis of (S)-2-hydroxy-2-methylbutyric acid via substrate engineering by using "thio-disguised" precursors and oxynitrilase catalysis (2007), Chemistry, 13, 3369-3376.
    View publication on PubMed
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Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
cyanide + benzaldehyde Prunus dulcis
-
 (R)-mandelonitrile
-
 ?

Organism

Organism UniProt Comment Textmining
Prunus dulcis
-
-
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
cyanide + 3-tetrahydrothiophenone the enzyme, that shows (R)-stereospecificity for its natural substrate shows S-stereselectivity with the heterocyclic ketone as substrate Prunus dulcis (S)-3-hydroxytetrahydrothiophene-3-carbonitrile
-
 ?
cyanide + benzaldehyde
-
 Prunus dulcis (R)-mandelonitrile
-
 ?

Synonyms

Synonyms Comment Organism
(R)-selective HNL
-
 Prunus dulcis
PaHNL
-
 Prunus dulcis