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Literature summary for 4.1.1.7 extracted from

  • Weiss, P.M.; Garcia, G.A.; Kenyon, G.L.; Cleland, W.W.; Cook, P.F.
    Kinetics and mechanism of benzoylformate decarboxylase using 13C and solvent deuterium isotope effects on benzoylformate and benzoylformate analogues (1988), Biochemistry, 27, 2197-2205.
    View publication on PubMed
Search for more literature for 4.1.1.7

Inhibitors

Inhibitors Comment Organism Structure
(R)-mandelate competitive Pseudomonas putida
(S)-Mandelate competitive Pseudomonas putida
2-carboxybenzaldehyde competitive Pseudomonas putida
Phenoxyacetate competitive Pseudomonas putida
phenylacetate competitive Pseudomonas putida
Phthalate competitive Pseudomonas putida
Phthalimide competitive Pseudomonas putida
trans-cinnamate competitive Pseudomonas putida

KM Value [mM]

KM Value [mM] KM Value Maximum [mM] Substrate Comment Organism Structure
0.056
-
 (p-methoxybenzoyl)formate
-
 Pseudomonas putida
0.059
-
 benzoylformate
-
 Pseudomonas putida
0.18
-
 [p-(Chloromethyl)benzoyl]formate
-
 Pseudomonas putida
0.19
-
 (p-methylbenzoyl)formate
-
 Pseudomonas putida

Organism

Organism UniProt Comment Textmining
Pseudomonas putida
-
-
-

Reaction

Reaction Comment Organism Reaction ID
phenylglyoxylate = benzaldehyde + CO2 the reaction has two partially rate-determining steps: initial tetrahedral adduct formation and decarboxylation Pseudomonas putida
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(p-methoxybenzoyl)formate
-
 Pseudomonas putida p-methoxybenzaldehyde + CO2
-
 ?
(p-methylbenzoyl)formate
-
 Pseudomonas putida p-methylbenzaldehyde + CO2
-
 ?
benzoylformate
-
 Pseudomonas putida benzaldehyde + CO2
-
 ?
[m-(Fluoromethyl)benzoyl]formate
-
 Pseudomonas putida ?
-
 ?
[p-(Chloromethyl)benzoyl]formate
-
 Pseudomonas putida ?
-
 ?

Cofactor

Cofactor Comment Organism Structure
thiamine diphosphate dependent on Pseudomonas putida