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Literature summary for 4.1.1.5 extracted from

  • Crout, D.H.G.; Littlechild, J.; Mitchell, M.B.; Morrey, S.M.
    Stereochemistry of the decarboxylation of alpha-acetolactate (2-hydroxy-2-methyl-3-oxobutanoate) by the acetolactate decarboxylase of Klebsiella aerogenes (1984), J. Chem. Soc. Perkin Trans. I, 1984, 2271-2276.
No PubMed abstract available
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Organism

Organism UniProt Comment Textmining
Klebsiella aerogenes
-
-
-

Reaction

Reaction Comment Organism Reaction ID
(2S)-2-hydroxy-2-methyl-3-oxobutanoate = (3R)-3-hydroxybutan-2-one + CO2 the carboxy group of alpha-acetolactate is replaced regiospecifically by hydrogen. This process takes place with overall inversion of configuration Klebsiella aerogenes
a

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
2-Hydroxy-2-methyl-3-oxobutanoate
-
 Klebsiella aerogenes (R)-3-Hydroxybutan-2-one + CO2
-
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