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Literature summary for 3.5.1.93 extracted from

  • Raimondi, S.; Forti, L.; Monti, D.; Riva, S.
    Kinetic resolutions of racemic amines and alcohols catalyzed by an industrial glutaryl-7-aminocephalosporanic acid acylase with unexpected broad substrate specificity (2003), Tetrahedron Asymmetry, 14, 1091-1094.
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
unidentified
-
purchased from Recordati, Milano
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
(5R,6R)-6-[(4-carboxybutanoyl)amino]-3,3-dimethyl-7-oxo-4-thia-1-azabicyclo[3.2.0]heptane-2-carboxylic acid + H2O 118% of the activity with glutaryl-7-aminocephalosporanic acid unidentified ?
-
?
(6R,7R)-7-[(3-carboxypropanoyl)amino]-3-methyl-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid + H2O 26.9% of the activity with glutaryl-7-aminocephalosporanic acid unidentified ?
-
?
(6R,7R)-7-[(3-carboxypropanoyl)amino]-8-oxo-3-(propionyloxy)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid + H2O 2.2% of the activity with glutaryl-7-aminocephalosporanic acid unidentified ?
-
?
(6R,7R)-7-[(4-carboxybutanoyl)amino]-3-methyl-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid + H2O 111% of the activity with glutaryl-7-aminocephalosporanic acid unidentified ?
-
?
(6R,7R)-7-[(5-carboxypentanoyl)amino]-3-methyl-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid + H2O 8.3% of the activity with glutaryl-7-aminocephalosporanic acid unidentified ?
-
?
(6R,7R)-7-[(5-carboxypentanoyl)amino]-8-oxo-3-(propionyloxy)-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid + H2O 6.9% of the activity with glutaryl-7-aminocephalosporanic acid unidentified ?
-
?
5-oxo-5-(1-phenylethoxy)pentanoic acid + H2O
-
unidentified glutarate + ?
-
?
5-oxo-5-[(1-phenylethyl)amino]pentanoic acid + H2O
-
unidentified ?
-
?
5-[(2-methoxy-1-phenylprop-2-en-1-yl)amino]-5-oxopentanoic acid + H2O
-
unidentified ?
-
?
5-[(2-methoxy-1-phenylprop-2-en-1-yl)oxy]-5-oxopentanoic acid + H2O
-
unidentified ?
-
?
glutaryl-7-aminocephalosporanic acid + H2O
-
unidentified 7-aminocephalosporanate + glutarate
-
?
N-glutaryl-D-alanine methyl ester + H2O 2.2% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + D-alanine methyl ester
-
?
N-glutaryl-D-phenylalanine + H2O 2% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + D-Phe
-
?
N-glutaryl-D-phenylalanine methyl ester + H2O 4.5% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + D-phenylalanine methyl ester
-
?
N-glutaryl-D-phenylglycine + H2O 1.1% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + D-phenylglycine
-
?
N-glutaryl-D-phenylglycine methyl ester + H2O 0.23% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + D-phenylglycine methyl ester
-
?
N-glutaryl-L-Ala + H2O 2.7% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + L-Ala
-
?
N-glutaryl-L-alanine methyl ester + H2O 25% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + L-alanine methyl ester
-
?
N-glutaryl-L-phenylalanine + H2O 2.5% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + L-Phe
-
?
N-glutaryl-L-phenylalanine methyl ester + H2O 15.7% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + L-phenylalanine methyl ester
-
?
N-glutaryl-L-phenylglycine + H2O 7.5% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + L-phenylglycine
-
?
N-glutaryl-L-phenylglycine methyl ester + H2O 59.3% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + L-phenylglycine methyl ester
-
?
N-glutarylglycine methyl ester + H2O 9.7% of the activity with glutaryl-7-aminocephalosporanic acid unidentified glutarate + glycine methyl ester
-
?

Synonyms

Synonyms Comment Organism
glutaryl-7-aminocephalosporanic acid acylase
-
unidentified