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Literature summary for 3.5.1.11 extracted from

  • Wu, W.B.; Wang, N.; Xu, J.M.; Wu, Q.; Lin, X.F.
    Penicillin G acylase catalyzed Markovnikov addition of allopurinol to vinyl ester (2005), Chem. Commun. (Camb.), 2005, 2348-2350.
    View publication on PubMed
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Application

Application Comment Organism
synthesis Markovnikov addition of allopurinol to vinyl ester by enzyme immobilized on acrylic beads. With vinyl acetate in dimethylsulfoxide, yield is about 60%. Decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate. Divinyl dicarboxylate reacts faster than the comparable mono-acid vinyl ester Escherichia coli

Organism

Organism UniProt Comment Textmining
Escherichia coli
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
allopurinol + vinyl acetate Markovnikov addition, decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate Escherichia coli 1-(4-oxo-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-1-yl)ethyl acetate
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allopurinol + vinyl decanoate Markovnikov addition, decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate Escherichia coli 1-(4-oxo-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-1-yl)ethyl decanoate
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allopurinol + vinyl pentanoate Markovnikov addition, decrease in activity in the order vinyl acetate, vinyl pentanoate, vinyl decanoate Escherichia coli 1-(4-oxo-4,5-dihydro-1H-pyrazolo[3,4-d]pyrimidin-1-yl)ethyl pentanoate
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