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Literature summary for 3.2.1.B26 extracted from
- Enzymatic synthesis of 2-deoxy-beta-glucosides and stereochemistry of beta-glycosidase from Sulfolobus solfataricus on glucal (2001), Tetrahedron Asymmetry, 12, 2783-2787.
No PubMed abstract available
Application
| Application | Comment | Organism |
|---|---|---|
| synthesis | synthesis of 2-deoxyglycosides and 2-deoxygalactosides from glucal or galactal as donors. The yields observed with alkyl acceptors confirms that the robustness of the biocatalyst is of great help in designing practical syntheses of pure beta-anomers of 2-deoxy derivatives of 4-penten-1-ol (obtained in 80% yield at 20 fold molar excess) and 3,4-dimethoxybenzyl alcohol (obtained in 19% yield at 3.3 fold molar excess). The attachment of 2-deoxyglyco units is performed on various pyranosidic acceptors (4-nitrophenyl alpha-D-glucopyranoside, 2-nitrophenyl 2-deoxy-N-acetyl-alpha-D-glucosamine and 4-nitrophenyl 2-deoxy-N-acetyl-beta-D-glucosamine). At low molecular excesses of the acceptors, satisfactory yields (20-40%) of chromophoric 2-deoxy di- and trisaccharides are obtained | Saccharolobus solfataricus |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| Saccharolobus solfataricus | - |
- |
- |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| Ss-beta-Gly | - |
Saccharolobus solfataricus |
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