Literature summary for 3.2.1.147 extracted from

Matusheski, N.V.; Swarup, R.; Juvik, J.A.; Mithen, R.; Bennett, M.; Jeffery, E.H.
Epithiospecifier protein from broccoli (Brassica oleracea L. ssp. italica) inhibits formation of the anticancer agent sulforaphane (2006), J. Agric. Food Chem., 54, 2069-2076.

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Organism

Organism	UniProt	Comment	Textmining
Brassica oleracea	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
(2S)-2-hydroxy-3-butenyl glucosinolate + H2O	i.e. epi-progoitrin	Brassica oleracea	D-glucose +	presence of endogenous epithiospecifier protein directs the reaction toward formation of an epithionitrile	?
4-(methylsulfinyl)butyl glucosinolate + H2O	i.e. glucoraphanin	Brassica oleracea	D-glucose + ?	presence of endogenous epithiospecifier protein directs the reaction toward formation of sulforaphane nitrile in place of the anticancerogenic sulforaphane	?

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Release 2023.1 (January 2023)