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Literature summary for 1.8.5.3 extracted from

  • Hernandez-Marin, E.; Ziegler, T.
    A kinetic study of dimethyl sulfoxide reductase based on density functional theory (2010), Can. J. Chem., 88, 683-693.
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
Rhodobacter capsulatus Q52675
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Reaction

Reaction Comment Organism Reaction ID
dimethylsulfide + menaquinone + H2O = dimethylsulfoxide + menaquinol according to density functional theory, the reaction between dimethyl sulfoxide and the model complex [Mo(OPh)(C2S2H2)2]- proceeds in one associative step. In the optimized transition state, the bond between the metal and dimethyl sulfoxide is being formed through the oxygen atom of dimethyl sulfoxide while the S-O bond in the substrate is weakening Rhodobacter capsulatus

Synonyms

Synonyms Comment Organism
DMSO reductase
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Rhodobacter capsulatus