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Literature summary for 1.8.3.1 extracted from
- Sulfur K-edge spectroscopic investigation of second coordination sphere effects in oxomolybdenum-thiolates: relationship to molybdenum-cysteine covalency and electron transfer in sulfite oxidase (2007), Inorg. Chem., 46, 1259-1267.
Crystallization (Commentary)
| Crystallization (Comment) | Organism |
|---|---|
| crystal structure of (3,5-dimethyltrispyrazol-1-yl)borate MoO(2-mercaptobenzyl alcohol), the first oxomolybdenum monothiolate to possess an Oax-Mo-Sthiolate-C dihedral angle of ca. 90° | synthetic construct |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| synthetic construct | - |
- |
- |
Substrates and Products (Substrate)
| Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
|---|---|---|---|---|---|---|
| additional information | Oax-Mo-Sthiolate-C dihedral angles near 90° effectively eliminate covalency contributions to the Mo(xy) redox orbital from the thiolate sulfur. The Oax-Mo-Sthiolate-C dihedral angle is shown to have a pronounced effect on the relative intensity ratios of the XAS spin-allowed S(1s)fSv(p) + Mo-(xy) and S(1s)fSv(p) + Mo(xz,yz) transitions | synthetic construct | ? | - |
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