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Literature summary for 1.21.99.5 extracted from
- Does catalysis of reductive dechlorination of tetra- and trichloroethylenes by vitamin B12 and corrinoid-based dehalogenases follow an electron transfer mechanism? (2005), J. Am. Chem. Soc., 127, 12154-12155.
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| synthetic construct | - |
- |
- |
Reaction
| Reaction | Comment | Organism | Reaction ID |
|---|---|---|---|
| trichloroethene + chloride + acceptor = tetrachloroethene + reduced acceptor | an electron transfer mechanism is not consistent with experimental data of rate constants. The actual mechanism involves more intimate interactions between the electron donor and the substrate in which the latter enters the cobalt coordination sphere | synthetic construct |
a
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