Literature summary for 1.13.11.60 extracted from

Hamberg, M.; Zhang, L.Y.; Brodowsky, I.D.; Oliw, E.H.
Sequential oxygenation of linoleic acid in the fungus Gaeumannomyces graminis: Stereochemistry of dioxygenase and hydroperoxide isomerase reactions (1994), Arch. Biochem. Biophys., 309, 77-80.

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Natural Substrates/ Products (Substrates)

Natural Substrates	Organism	Comment (Nat. Sub.)	Natural Products	Comment (Nat. Pro.)	Rev.	Reac.
linoleate + O2	Gaeumannomyces graminis	i.e. (9Z,12Z)-octadeca-9,12-dienoate	(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	?
linoleate + O2	Gaeumannomyces graminis var.graminis	i.e. (9Z,12Z)-octadeca-9,12-dienoate	(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	?

Organism

Organism	UniProt	Comment	Textmining
Gaeumannomyces graminis	-	-	-

Substrates and Products (Substrate)

Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
linoleate + O2	i.e. (9Z,12Z)-octadeca-9,12-dienoate	Gaeumannomyces graminis	(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	?
linoleate + O2	i.e. (9Z,12Z)-octadeca-9,12-dienoate. The dioxygenase reaction involves stereospecific abstraction of the pro-S hydrogen from C-8 followed by antarafacial insertion of dioxygen to produce (8R)-hydroperoxylinoleic acid	Gaeumannomyces graminis	(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	?
linoleate + O2	i.e. (9Z,12Z)-octadeca-9,12-dienoate	Gaeumannomyces graminis var.graminis	(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	?
linoleate + O2	i.e. (9Z,12Z)-octadeca-9,12-dienoate. The dioxygenase reaction involves stereospecific abstraction of the pro-S hydrogen from C-8 followed by antarafacial insertion of dioxygen to produce (8R)-hydroperoxylinoleic acid	Gaeumannomyces graminis var.graminis	(8R,9Z,12Z)-8-hydroperoxy-9,12-octadecadienoate	-	?

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Release 2023.1 (January 2023)