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Literature summary for 1.13.11.53 extracted from

  • Allpress, C.; Berreau, L.
    A nickel-containing model system of acireductone dioxygenases that utilizes a C(1)-H acireductone substrate (2014), Eur. J. Inorg. Chem., 2014, 4642-4649 .
No PubMed abstract available

Organism

Organism UniProt Comment Textmining
synthetic construct
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Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
additional information a mononuclear NiII complex bearing the monoanion of 1-acetoxy-3-phenylpropane-2,3-dione as a ligand, i.e. (N,N-bis[(6-phenyl-2-pyridyl)methyl]-N-(2-pyridylmethyl)amine)Ni[PhC(O)C(O)CHOC(O)CH3]ClO4 after deprotection by the addition of NaOCH3 in methanol generates a NiII species that contains a coordinated dianionic C(1)-H acireductone. Exposure of this acireductone to O2 leads to regioselective oxidative cleavage reactivity akin to that found for the NiII-containing acireductone dioxygenase enzyme synthetic construct ?
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