Valdez, C.; Gallup, N.; Alexandrova, A.
Co2+ acireductone dioxygenase Fe2+ mechanism, Ni2+ mechanism, or something else? (2014), Chem. Phys. Lett., 604, 77-82 .
No PubMed abstract available
Crystallization (Commentary)
Crystallization (Comment) |
Organism |
quantum-classical dynamics simulations with Co2+ bound. Both Fe2+-like (reaction of EC 1.13.11.54) and Ni2+-like (reaction of EC 1.13.11.53) routes are accessible to Co2+-ARD. with low spin Co2+, the reaction exclusively follows the Fe2+-dependent pathways, producing alpha-keto acid precursor of methionine and formate, while the high spin Co2+ path contains a bifurcation in the pathway that follows along both the Fe2+-dependent pathway and Ni2+-dependent pathway that produces methylthiopropionate, carbon monoxide and formate |
Klebsiella oxytoca |
Metals/Ions
Metals/Ions |
Comment |
Organism |
Structure |
Co2+ |
quantum-classical dynamics simulations with Co2+ bound. both Fe2+-like (reaction of EC 1.13.11.54) and Ni2+-like (reaction of EC 1.13.11.53) routes are accessible to Co2+-ARD, but the mechanism involves a bifurcating transition state, and so the exact product distribution is determined by the reaction dynamics |
Klebsiella oxytoca |
|
Organism
Organism |
UniProt |
Comment |
Textmining |
Klebsiella oxytoca |
Q9ZFE7 |
- |
- |
Synonyms
Synonyms |
Comment |
Organism |
MtnD |
- |
Klebsiella oxytoca |