Literature summary for 1.13.11.24 extracted from

Hoof, S.; Limberg, C.
The behavior of trispyrazolylborato-metal(II)-flavonolate complexes as functional models for bacterial quercetinase-assessment of the metal impact (2019), Inorg. Chem., 58, 12843-12853 .

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Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

General Information

General Information	Comment	Organism
metabolism	compounds TpMesMFla (TpMes = hydrotris(3-mesityl)pyrazolylborate, M = Mn, Fe, Co, Ni, Zn, Fla = 3-hydroxyflavonolate) as models for 2,4-quercetin dioxygenase. The structures differ in the degree of delocalization in the chelate ring formed through the binding of the two O donors of the flavonolate to the metal center, the resulting trend (Zn/Fe > Co > Mn > Ni) is, not in line with the one that found when investigating the redox properties of the complexes by cyclic voltammetry (Zn > Fe > Ni > Co > Mn). The complexes exhibit exceptionally well-behaved quasi-reversible redox transitions. After the O2 reaction, salicylic acid is one of the products	synthetic construct

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Release 2023.1 (January 2023)