Literature summary for 1.13.11.24 extracted from

Sun, Y.; Liu, Y.; Zhang, J.; Li, Y.
Structure-reactivity relationship in ES models of Co(II)-containing quercetin 2,4-dioxygenase (2019), ChemistrySelect, 4, 13974-13982 .

No PubMed abstract available

Search for more literature for 1.13.11.24

Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

General Information

General Information	Comment	Organism
metabolism	design of model ligands 2NCOO, 3 N, 3NCOO, 4 N (L2NCOOH: 2-((benzyl(pyridin-2-ylmethyl)amino)methyl)benzoic acid, L3N: N-benzyl-1-(pyridin-2-yl)-N-(pyridin-2-ylmethyl)methanamine, L3NCOOH: 2-{[bis(pyridin-2-ylmethyl)amino]methyl}benzoic acid, L4N: tris(pyridin-2-ylmethyl)amine) and their complexes [CoIILn(fla)] (n: 2NCOO (1), 3 N (2), 3NCOO (3), 4 N (4); fla: 3-flavonolate) as ES models of the Co(II)-containing quercetin 2,4-dioxygenase. [CoLn(fla)] exhibits higher single turnover O2 reactivity to produce products similar to the enzymatic reaction, and the decreasing order of reactivity is 3 > 4 > 1 > 2. The reaction rate constant k shows linear correlation with E1/2(CoIII/II) and Epa(fla-/fla radical)	synthetic construct

Use of this online version of BRENDA is free under the CC BY 4.0 license. See terms of use for full details.

Release 2023.1 (January 2023)