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Literature summary for 1.12.99.6 extracted from
- Redox and structural properties of mixed-valence models for the active site of the [FeFe]-hydrogenase: progress and challenges (2008), Inorg. Chem., 47, 7405-7414.
Metals/Ions
| Metals/Ions | Comment | Organism | Structure |
|---|---|---|---|
| Fe | the Fe(CO)2(Pi-Pr3) site is rotated in solution, driven by steric factors. Fe atom featuring a vacant apical coordination position is an electrophilic Fe(I) center. One-electron oxidation of [Fe2(S2C2H4)(CN)(CO)3(dppv)]- results in 2e oxidation of 0.5 equiv to give the micro-cyano derivative [FeI2(S2C2H4)(CO)3(dppv)](micro-CN)[FeII2(S2C2H4)(micro-CO)(CO)2(CN)(dppv)] | synthetic construct |  |
Organism
| Organism | UniProt | Comment | Textmining |
|---|---|---|---|
| synthetic construct | - |
- |
- |
Synonyms
| Synonyms | Comment | Organism |
|---|---|---|
| [FeFe]-hydrogenase | - |
synthetic construct |
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