Metals/Ions | Comment | Organism | Structure |
---|---|---|---|
Fe | protonation can take place in a terminal fashion at a single Fe or by bridging between two iron centres, protonation of a model of the subsite of [FeFe]-hydrogenase, [Fe2(m-pdt)(CO)4(PMe3)2], occurs via a two-step mechanism | synthetic construct |
Organism | UniProt | Comment | Textmining |
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synthetic construct | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
additional information | protonation of a model of the subsite of [FeFe]-hydrogenase, [Fe2(micro-pdt)(CO)4(PMe3)2]. The deceptively simple stoichiometric reaction is limited by the rate of protonation of the basal-apical isomer followed by its rearrangement to the transoid basal form | synthetic construct | ? | - |
? |
Synonyms | Comment | Organism |
---|---|---|
[FeFe] hydrogenase | - |
synthetic construct |
General Information | Comment | Organism |
---|---|---|
physiological function | protonation is a fundamental step in hydrogen evolution at the di-iron subsite of [FeFe]-hydrogenase | synthetic construct |