KM Value [mM] | KM Value Maximum [mM] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
0.0001 | - |
R-(+)-limonene | pH 6, in presence of Cl- | Leptoxyphium fumago | |
0.00011 | - |
R-(+)-limonene | pH 3, in presence of Cl- | Leptoxyphium fumago | |
0.00034 | - |
R-(+)-limonene | pH 6, without Cl- | Leptoxyphium fumago | |
0.00036 | - |
R-(+)-limonene | pH 3, without Cl- | Leptoxyphium fumago |
Organism | UniProt | Comment | Textmining |
---|---|---|---|
Leptoxyphium fumago | - |
- |
- |
Substrates | Comment Substrates | Organism | Products | Comment (Products) | Rev. | Reac. |
---|---|---|---|---|---|---|
(R)-limonene + H2O2 | when the reaction is carried out in the presence of chloride ions an enhancement in the reaction rate is observed, maintaining the regioselectivity, but not the stereoselectivity. The reaction products under these conditions are (1S,2S)-4R-limonene-1,2-diol and (1R,2R)-4R-limonene-1,2-diol. In the presence of potassium chloride the limonene oxidation also occurs by the produced hypochlorite without stereoselectivity | Leptoxyphium fumago | (1S,2S,4R)-limonene-1,2-diol + (1R,2R)-4R-limonene-1,2-diol + ? | - |
? | |
(R)-limonene + H2O2 | in the absence of chloride ions, at pH 3 or pH 6, the reaction is regio and stereoselective with a diasteromeric excess of more than 99% of (1S,2S)-4R-limonene-1,2-diol | Leptoxyphium fumago | (1S,2S,4R)-limonene-1,2-diol + H2O | - |
? |
Turnover Number Minimum [1/s] | Turnover Number Maximum [1/s] | Substrate | Comment | Organism | Structure |
---|---|---|---|---|---|
2.3 | - |
(R)-limonene | pH 3, without Cl- | Leptoxyphium fumago | |
11.1 | - |
(R)-limonene | pH 6, in presence of Cl- | Leptoxyphium fumago | |
11.8 | - |
(R)-limonene | pH 6, without Cl- | Leptoxyphium fumago | |
18.7 | - |
(R)-limonene | pH 3, in presence of Cl- | Leptoxyphium fumago |