Literature summary for 1.1.3.9 extracted from

Oshita, H.; Suzuki, T.; Kawashima, K.; Abe, H.; Tani, F.; Mori, S.; Yajima, T.; Shimazaki, Y.
Pi-pi stacking interaction in an oxidized CuII -salen complex with a side-chain indole ring an approach to the function of the tryptophan in the active site of galactose oxidase (2019), Chemistry, 25, 7649-7658 .

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Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

General Information

General Information	Comment	Organism
metabolism	the indole ring, as an electron donor, stabilizes the phenoxyl radical by the pi-pi stacking interaction. A CuII complex of a methoxy-substituted salen-type ligand, containing a pendent indole ring on the dinitrogen chelate backbone exhibits the pi-pi stacking interaction of the indole ring mainly with one of the two phenolate moieties. The phenolate moiety in close contact with the indole moiety shows the characteristic phenoxyl radical structural features, indicating that the indole ring favors the pi-pi stacking interaction with the phenoxyl radical	synthetic construct

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Release 2023.1 (January 2023)