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Literature summary for 1.1.1.260 extracted from

  • Tidswell, E.C.; Salter, G.J.; Kell, D.B.; Morris, J.G.
    Enantioselectivity of sulcatone reduction by some anaerobic bacteria (1997), Enzyme Microb. Technol., 21, 143-147.
No PubMed abstract available

Natural Substrates/ Products (Substrates)

Natural Substrates Organism Comment (Nat. Sub.) Natural Products Comment (Nat. Pro.) Rev. Reac.
6-methylhept-5-en-2-one + NADH Clostridium tyrobutyricum enantiomeric selectivity substantially affected by pregrowth period and substrate concentration 6-methylhept-5-en-2-ol + NAD+ sulcatol r
6-methylhept-5-en-2-one + NADH Levilactobacillus brevis sulcatone 6-methylhept-5-en-2-ol + NAD+ sulcatol r
6-methylhept-5-en-2-one + NADH Clostridium tyrobutyricum sulcatone 6-methylhept-5-en-2-ol + NAD+ sulcatol r
6-methylhept-5-en-2-one + NADH Levilactobacillus brevis R(-)-sulcatol in high enantiomeric excess formed irrespective of pregrowth period and substrate concentration 6-methylhept-5-en-2-ol + NAD+ sulcatol r

Organism

Organism UniProt Comment Textmining
Clostridium tyrobutyricum
-
strains AuxP, PON5
-
Levilactobacillus brevis
-
-
-

Source Tissue

Source Tissue Comment Organism Textmining
cell culture
-
Levilactobacillus brevis
-
cell culture
-
Clostridium tyrobutyricum
-

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
6-methylhept-5-en-2-one + NADH enantiomeric selectivity substantially affected by pregrowth period and substrate concentration Clostridium tyrobutyricum 6-methylhept-5-en-2-ol + NAD+ sulcatol r
6-methylhept-5-en-2-one + NADH sulcatone Levilactobacillus brevis 6-methylhept-5-en-2-ol + NAD+ sulcatol r
6-methylhept-5-en-2-one + NADH sulcatone Clostridium tyrobutyricum 6-methylhept-5-en-2-ol + NAD+ sulcatol r
6-methylhept-5-en-2-one + NADH R(-)-sulcatol in high enantiomeric excess formed irrespective of pregrowth period and substrate concentration Levilactobacillus brevis 6-methylhept-5-en-2-ol + NAD+ sulcatol r

Cofactor

Cofactor Comment Organism Structure
NADH
-
Levilactobacillus brevis
NADH
-
Clostridium tyrobutyricum