Information on EC 4.2.3.58 - longifolene synthase

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The expected taxonomic range for this enzyme is: Picea abies

EC NUMBER
COMMENTARY
4.2.3.58
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RECOMMENDED NAME
GeneOntology No.
longifolene synthase
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REACTION
REACTION DIAGRAM
COMMENTARY
ORGANISM
UNIPROT ACCESSION NO.
LITERATURE
(2E,6E)-farnesyl diphosphate = longifolene + diphosphate
show the reaction diagram
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-
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PATHWAY
KEGG Link
MetaCyc Link
oleoresin sesquiterpene volatiles biosynthesis
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Sesquiterpenoid and triterpenoid biosynthesis
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SYSTEMATIC NAME
IUBMB Comments
(2E,6E)-farnesyl-diphosphate diphosphate-lyase (longifolene-forming)
As well as 61% longifolene the enzyme gives 15% of alpha-longipinene, 6% longicyclene and traces of other sesquiterpenoids.
ORGANISM
COMMENTARY
LITERATURE
SEQUENCE CODE
SEQUENCE DB
SOURCE
Norway spruce
SwissProt
Manually annotated by BRENDA team
SUBSTRATE
PRODUCT                      
REACTION DIAGRAM
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
(Substrate)
LITERATURE
(Substrate)
COMMENTARY
(Product)
LITERATURE
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
show the reaction diagram
-, Q675L0
-
main product
-
?
(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
show the reaction diagram
Picea abies Karst
-
-
main product
-
?
additional information
?
-
-, Q675L0
longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
-
-
-
additional information
?
-
Picea abies Karst
-
longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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NATURAL SUBSTRATES
NATURAL PRODUCTS
REACTION DIAGRAM
ORGANISM
UNIPROT ACCESSION NO.
COMMENTARY
(Substrate)
LITERATURE
(Substrate)
COMMENTARY
(Product)
LITERATURE
(Product)
REVERSIBILITY
r=reversible
ir=irreversible
?=not specified
(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
show the reaction diagram
-, Q675L0
-
main product
-
?
(2E,6E)-farnesyl diphosphate
longifolene + diphosphate
show the reaction diagram
Picea abies Karst
-
-
main product
-
?
additional information
?
-
-, Q675L0
longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
-
-
-
additional information
?
-
Picea abies Karst
-
longifolene synthase gives besides the main product longifolene (60.6% yield) alpha-longipinene (14.6%), longicyclene (5.9%), (E)-beta-farnesene (3.4%), longiborneol (2.1%), cyclosativene (1.3%), beta-longipinene (1.4%) and other sesquiterpenes (less than 1.4% each)
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