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geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
()-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
()-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
-
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]. For the geminal methyl groups C16 and C17 of geranylgeranyl diphosphate the enzyme shows a strictly controlled stereochemical course, as observed for most terpene cyclases. No activity with geranyl diphosphate and farnesyl diphosphate
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
-
-
-
?
geranylgeranyl diphosphate
(-)-spiroviolene + diphosphate
-
(-)-spiroviolene i.e. (2R,3a'S,3b'R,5R,6a'R)-2,4',4',5,6a'-pentamethyl-2',3',3a',3b',4',5',6',6a'-octahydrospiro[cyclopentane-1,1'-cyclopenta[a]pentalene]. For the geminal methyl groups C16 and C17 of geranylgeranyl diphosphate the enzyme shows a strictly controlled stereochemical course, as observed for most terpene cyclases. No activity with geranyl diphosphate and farnesyl diphosphate
-
-
?
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