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Information on EC 3.7.1.18 - 6-oxocamphor hydrolase and Organism(s) Rhodococcus sp and UniProt Accession Q93TU6

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EC Tree
     3 Hydrolases
         3.7 Acting on carbon-carbon bonds
             3.7.1 In ketonic substances
                3.7.1.18 6-oxocamphor hydrolase
IUBMB Comments
Isolated from Rhodococcus sp. The bornane ring system is cleaved by a retro-Claisen reaction to give the enol of alpha-campholonate. When separate from the enzyme the enol is tautomerised to the keto form as a 6:1 mixture of [(1S,3R)-2,2,3-trimethyl-4-oxocyclopentyl]acetate and [(1S,3S)-2,2,3-trimethyl-4-oxocyclopentyl]acetate.
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This record set is specific for:
Rhodococcus sp
UNIPROT: Q93TU6
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Word Map
The enzyme appears in selected viruses and cellular organisms
Synonyms
6-oxocamphor hydrolase, 6-oxo camphor hydrolase, more
SYNONYM
ORGANISM
UNIPROT
COMMENTARY hide
LITERATURE
CaMK
-
-
-
-
OCH
-
-
-
-
SYSTEMATIC NAME
IUBMB Comments
bornane-2,6-dione hydrolase
Isolated from Rhodococcus sp. The bornane ring system is cleaved by a retro-Claisen reaction to give the enol of alpha-campholonate. When separate from the enzyme the enol is tautomerised to the keto form as a 6:1 mixture of [(1S,3R)-2,2,3-trimethyl-4-oxocyclopentyl]acetate and [(1S,3S)-2,2,3-trimethyl-4-oxocyclopentyl]acetate.
UNIPROT
ENTRY NAME
ORGANISM
NO. OF AA
NO. OF TRANSM. HELICES
MOLECULAR WEIGHT[Da]
SOURCE
SEQUENCE
LOCALIZATION PREDICTION?
CAMK_RHOSO
Rhodococcus sp
257
0
28483
Swiss-Prot
-