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Information on EC 1.14.19.34 - acyl-lipid (9+3)-(E)-desaturase

for references in articles please use BRENDA:EC1.14.19.34
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EC Tree
IUBMB Comments
The enzymes from the plants Dimorphotheca sinuata (African daisy) and Vernicia fordii (tung oil tree) insert a trans double bond in position C-12 of oleate and palmitoleate incorporated into glycerolipids. The enzyme introduces the new double bond at a position three carbons away from an existing double bond at position 9, towards the methyl end of the fatty acid. The enzyme from tung oil tree also possesses the activity of EC 1.14.19.33, Delta12 acyl-lipid conjugase.
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The enzyme appears in viruses and cellular organisms
Synonyms
dsfad2-2, dsfad2-1, delta12-oleic acid desaturase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
a palmitoleoyl-[glycerolipid] + 2 ferrocytochrome b5 + O2 + 2 H+ = a (9Z,12E)-hexadeca-9,12-dienoyl-[glycerolipid] + 2 ferricytochrome b5 + 2 H2O
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(2)
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an oleoyl-[glycerolipid] + 2 ferrocytochrome b5 + O2 + 2 H+ = a (9Z,12E)-octadeca-9,12-dienoyl-[glycerolipid] + 2 ferricytochrome b5 + 2 H2O
show the reaction diagram
PATHWAY SOURCE
PATHWAYS
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